Amorphous Materials Inc.

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GALLIUM ARSENIDE

 Gallium Arsenide is prepared at Amorphous Materials by two methods: Horizontal Bridgman and Vertical Bridgman. Materials may be doped or undoped, single or polycrystalline. IR optical lens blanks are furnished as semi-insulating material. All material is 100% tested to assure an absorption coefficient of 0.01 cm -1 or less. Laser calorimetry measurements are used to verify the quality of high energy laser grade material. Large area rectangular windows, up to 6" x 12" , are prepared using a Horizontal Bridgman technique. The material can be doped or undoped materials may be provided.

GENERAL PROPERTIES OF GALLIUM ARSENIDE

Density 5.31 gms/cm3
Thermal Expansion 6 X 10-6/ºC
Hardness (Knoop) 750
Rupture Modulus 10,436 psi
Thermal Conductivity 0.37 W/ cm sec ºK
Specific Heat 0.076 cal / gm ºK
Molecular Weight 144.63
Structure cubic
Melting Point 1238ºC
Dielectric Constant 12.5
Energy Gap 1.38 ev @ 25ºC

 

 

 

WAVELENGTH

µm

REFRACTIVE (1)

INDEX @ 25º C

ABSORPTION

COEFFICIENT cm-1

1.0 3.5091 1.74
1.064 3.4774 1.41
1.25 3.4188 0.45
1.50 3.3777 0.061
1.75 3.3549 0.011
2.0 3.3409 0.01
2.5 3.3256 0.01
3 3.3161 0.01
4 3.3066 0.01
5 3.3010 0.01
6 3.2966 0.01
7 3.2924 0.01
8 3.2881 0.01
9 3.2834 0.01
10 3.2782 0.01
11 3.2725 0.01
12 3.2661 0.03
13 3.2589 0.41
14 3.2508 0.23

V3-5 = 145 V8-12 = 107

Measured optical homogeneity for 100mm diameter plates 50mm thick was

± 65 X 10-6 or DN/N = 20 X 10-6 (Scott Sullivan, Exotic Materials, 1991)

(1) Hilton (1975), Horizontal Bridgman, Parrallel to Growth Axis

THERMAL CHANGE IN REFRACTIVE INDEX DN / D T ºC X 106

Wavelength µm (LOW) (HIGH )
3 161±4 206±1
5 159±5 216±3
8 157±5 208±11
10 148±7 202±14
12 153±6 210±15

 

GaAs MSD.pdf